How to Create Mail-Merged Labels in Word 2013 - dummies In Word, press Ctrl+N to start a new blank document and then choose Mailings→Start Mail Merge→Labels. The Label Options dialog box appears. From the Label Vendors drop-down list, choose Avery us Letter; in the Product Number list, choose 5160 Easy Peel Address Labels; click OK. Almost every size and shape of label has a code on the ...